Date of Award

2010-01-01

Degree Name

Master of Science

Department

Mechanical Engineering

Advisor(s)

Jack F. Chessa

Abstract

Presented is an ab-initio Molecular Dynamics (MD) study, employing the Density Functional Theory (DFT), of the lattice parameter, thermal expansion coefficients and elastic constants of ZrB2, TiB2 and HfB2 as a function of temperature. The MD trajectories provide the equilibrium lattice parameters at finite temperatures, and the gradient of the energy from these equilibrium solutions is then used to calculate the components of the stiffness tensor. The results for ZrB2 are shown to agree well with reported experimental results for the lattice parameters and elastic constants as a function of temperature.

Language

en

Provenance

Received from ProQuest

File Size

112 pages

File Format

application/pdf

Rights Holder

Manny Gonzales

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