Gravimetrically characterizable common alkali reducing agents and ligand design of a new electron rich guanidinate
Synthesis, isolation and characterization of 12 new alkali arenides was performed by the addition of the chelating base 18-crown-6. Electrochemistry, UV-vis/NIR spectroscopy and XRD studies were performed. The incorporation of an imidazolin-2-iminato group to the background of a guanidinate showed that this kind of ligand is electronically flexible and metal dependent. It was found that is more electron donating than some previously reported guanidinates and ketimine guanidinates.
Chemistry|Inorganic chemistry|Organic chemistry
Castillo Noris, Efrain Maximiliano, "Gravimetrically characterizable common alkali reducing agents and ligand design of a new electron rich guanidinate" (2016). ETD Collection for University of Texas, El Paso. AAI10151167.