Date of Award
Master of Science
SynThesis, isolation and characterization of 12 new alkali arenides was performed by the addition of the chelating base 18-crown-6. Electrochemistry, UV-vis/NIR spectroscopy and XRD studies were performed.
The incoorporation of an imidazolin-2-iminato group to the background of a guanidinate showed that this kind of ligand is electronically flexible and metal dependent. It was found that is more electron donating than some previously reported guanidinates and ketimine guanidinates.
Received from ProQuest
Efrain Maximiliano Castillo
Castillo, Efrain Maximiliano, "Gravimetrically Characterizable Common Alkali Reducing Agents And Ligand Design Of A New Electron Rich Guanidinate" (2016). Open Access Theses & Dissertations. 820.